Steam Boiler Amines: Neutralizing & Film-Forming

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Steam Boiler Amines
Neutralizing & Film-Forming

The condensate lines in steam boilers are prone to corrosion. This is due to condensate water in the steam boiler reacting with carbon dioxide (CO2). This reaction can form carbonic acid, which corrodes the metal condensate line piping. The solution for this is to use amine chemicals in the condensate lines.

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There are two main types of boiler amines: neutralizing and film-forming.

Neutralizing Amines

Neutralizing amines increase boiler pH and help “neutralize” carbonic acid. It is important to maintain a pH in a range of 7.5-9, as these amines can be corrosive to copper in other conditions. Neutralizing amines dissolve completely in water. The steam can also carry them throughout the boiler system. There are different amine ranges you can purchase based on how far you need the amine to travel in the system. You can inject the chemical into the feedwater tank.

Common Neutralizing Amine Chemicals

Morpholine

Cyclohexylamine

Diethylaminoethanol

Filming Amines

Undamaged metal surface 
thanks to a waterphobic filming amine. VS Rusted metal boiler surface with no amines.

Filming amines creates a monomolecular film which acts as a protective layer from carbonic acid corrosion. Filming amines do not dissolve in water like neutralizing amines; due to this, you need to feed them into the steam header to carry them throughout the system. It is important to gradually feed filming amines, especially in steam boilers with corrosion deposits and oxygen leaks. It could build up in certain areas of the piping otherwise. The way filming amines work to prevent corrosion in condensate lines is by being hydrophobic. The amine binds closely to the metal piping while repelling the water away from the metal surface.

Common Filming Amine Chemicals

Octadecylamine (ODA)

Ethoxylated Soya Amine (ESA)

Using Both Amines and Oxygen Scavenger Chemicals in Steam Boilers?

2 Corrosion Prevention Chemcials?
Utilizing both amines and oxygen scavengers allows you to receive the benefits from both. The amine protects from the harmful acids. The oxygen scavengers help prevent oxygen from forming.

You can use amines and oxygen scavengers together to help prevent corrosion effectively in steam boilers. As mentioned previously, amines passivate metal surfaces / form a protective layer. Oxygen scavengers remove oxygen from water. These are both ways to prevent corrosion in steam boiler condensate lines, and when used together, it is incredibly effective. There is a chemical called Diethylhydroxylamine (DEHA) that mixes amines and oxygen scavengers together. It is made from a reaction of an amine called triethylamine and a peroxide.

Benefits of Amines in Steam Boilers

  • The primary benefit of amines in steam boilers is for corrosion prevention. Corrosion can cause serious issues such as leaky pipes and rusty, ineffective heat exchangers.
  • Increased efficiency is a major benefit of amines. Corrosion on heat exchangers causes impeded heat transfer, as the metal is not as conductive and has layers of oxidation. This reduction in conductivity means increased energy costs to transfer heat.
  • Maintenance costs are significantly reduced. How much would it cost to replace an inefficient boiler or portion of the condensate pipe? Additionally, it offers protection during layups and startups, which is a period where a lot of corrosion occurs for a steam boiler.

Amines for Healthcare Steam Boilers

Steam boilers have multiple applications in a healthcare setting. This can include steam sterilization, humidifying, and heating. If it is used as a humidifier, it must comply with ANSI/ASHRAE Standard 170-2013 Ventilation of Health Care Facilities / FDA regulations 21 CFR 173.310 Boiler Water Additives. Basically, the amine chemical must be considered “food-safe” in case it comes in contact with food or is breathed in by patients or workers. Just like other applications, hospitals and other healthcare facilities need to prevent corrosion in their boilers, and amines are an effective way to do that.

Steam Boiler Amine Chemical Treatment Services

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Chardon Labs utilizes amines, corrosion inhibitors, scale inhibitors, pH adjusters, and other chemicals to effectively treat steam boilers. We routinely feed chemicals to ensure that your system always has treatment. Additionally, we use remote monitoring equipment to check up on your system, carefully examining the chemistry of your water to help prevent problems and improve system efficiency. To learn more about our offerings and book an appointment, go here.

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Matt Welsh

Matt Welsh is the Vice President and Water Consultant at Chardon Labs. He helps consult a wide range of customers utilizing various methods of water treatment, from chemical to chemical-free approaches, large and small applications, and across a wide range of geographical influences. With 20 years of water treatment experience, including a wide range of troubleshooting and service in potable water and non-potable HVAC and industrial applications, he is an expert in water treatment chemistry for cooling towers, boilers, and closed-loop systems.

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